METX : ENGINE FORMULA
MATERIAL SAFETY DATA SHEET (MSDS)
1. IDENTIFICATION OF THE
SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of the
Substance of Preparation
Product Code: 98101
Product Name: Metal Treatment Solution
Product Type: Liquid
Product Description: Metal treatment Solution
Synonyms: Metal
Treatment
Reach Registration: To be determined
Recommended Use & Limits Low Odour
Extreme Pressure Metal Surface Additive Applications: Diesel/Gasoline Engine:
Automotive, Marine & Small Displ. Engines, Metal-working, bearings,
Generators
Company undertaking
identification:
Company
Name: AVRO Solutions Pte Ltd
126
Aljunied Rd
Singapore
380126
2. HAZARDS IDENTIFICATION
Classification
|
|
Flammable Liquids
|
Category 4
|
Skin Corrosion/irritation
|
Category 3
|
Germ Cell Mutagenicity
|
Category 1B
|
Carcinogenicity
|
Category 1B
|
Aspiration Toxicity
|
Category 1
|
Acute Aquatic
|
Category 2
|
GHS Hazard Phrases
H227: Combustible
Liquid
H303: May be harmful if
swallowed or enters airways
H316: Causes mild skin
irritation
H350: May cause cancer
H402: Harmful to
aquatic life
H412: Harmful to
aquatic life with long lasting effects
GHS Precaution Phases
P201: Obtain Special
instructions before use
P202: Do not hand until
safety instruction have been read and understood
P210: Keep away from
heat/spark/open flame and hot Surfaces. No smoking
P273: Avoid release to
the environment
P280: Wear Protective
Gloves/protective clothing, eye and face protection
GHS Response Phrases
P301+310: If Swallowed:
Immediately call a Poison Center or doctor/physician
P308+313: If exposed or
concerned get medical help
P331: Do not induce
Vomiting
P332+378: If skin
irritation occurs get medical advice
P370+378: In case of
fire, use approved material to extinguish
GHS Storage
P403+235: Store in a
cool well ventilated place
Disposal Phases
P501: Dispose of
contents/container to approved locations in compliance with all applicable
regulations
OSHA Regulatory Status:
This material is classified as hazardous under OSHA Regulations
3. COMPOSTION / INFORMATION
ON INGREDIENTS
CAS#
|
Partial
Chemical Name
|
Percent
|
EINECS
|
64742-47-8
|
Hydrotreated Light Distilate
|
6-27%
|
232-366-4
|
72623-86-0
|
Lubricating Oil C15-C30
|
5-25%
|
265-156-6
|
63449-39-8
|
Alpha OlephinsAlkene
|
30-55%
|
500-183-1
|
61789-86-4
|
Synthetic Calcium Sulfonates
|
2-7%
|
No Data
|
9002-84-0
|
Ethene, Tetrafluoro, Hoopolymer
|
1-5%
|
265-149-8
|
4. FIRST AID MEASURES
Emergency and First Aid
Procedures:
In
Case of Inhalation:
Remove to fresh air. If not breathing,
institute rescue breathing. If breathing is difficult, ensure airway is clear
and given oxygen. If hear is stopped, immediately begin cardiopulmonary
resuscitation (CPR). Keep affected person warn and at rest. Get Immediate
Medical Attention.
In
Case of Skin Contact:
Immediately wash exposed skin with soap
and water while removing contaminated clothing and shoes. Get medical attention
if irritation exists. Place contaminated clothing in a closed container until
cleaned or discarded. If clothing is to be laundered, inform the person
performing the operation of contaminant’s hazardous properties.
In
Case of Eye Contact:
Flush immediately with large amounts of
water for at least 15 minutes. Eyelids should be held away for the eyeball to
insure thorough rinsing. Get immediate medical attention.
In
Case of Ingestion:
Do not induce vomiting. If spontaneous
vomiting is about to occur, place victim’s head below his or her knees. If
victim is drowsy or unconscious, place on the left side with head down. Never
give anything by mouth to an unconscious person. Keep affective person warm and
at rest until medical aid arrives. Get immediate medical attention.
Note
to Physician:
Provide
general supportive measures and treat symptomatically. Treat symptomatically.
Keep victim under close observation. Symptoms may be delayed. If ingested this
material represents an aspiration and chemical pneumonitis hazard. Induction of
emesis is not recommended
5. FIRE FIGHTING MEASURES
Flash
Point: 83.00 C (181.4 F)
Method used. PMCC
Explosive
Limits:
LEL: No Data UEL: No Data
Auto
Ignition: No Data
Suitable
Extinguisher Media:
For small fires, Class B fire
extinguishing media such as CO2, dry chemical, foam (AFFF/ATC) or water spray
can be used. For large fires, water spray, fog or foam (AFF/ATC) can be used.
Firefighting should be attempted only both those who are adequately trained and
equipped with proper protective equipment.
Unsuitable
Extinguishing Media:
Do
not use water jet as an extinguisher as this will spread the fire.
Firefighting Instructions:
Firefighters should wear
appropriate protective equipment and self-contained breathing apparatus (SCBA)
with full face-piece operated in positive pressure mode. Avoid using straight
water streams. Water spray and foam (AFFF/ATC) must be applied carefully to
avoid frothing and from as far a distance as possible. Avoid excessive water
spray application. Keep surrounded area cool with water spray from a distance
and prevent further ignition of combustible material. Keep run-off water out of
sewers and water sources.
Hazardous Combustion Products:
Smoke,
carbon dioxide, carbon monoxide, oxides of low aromatic or other hydrocarbons
and other product of incomplete combustion.
6. ACCIDENTAL RELEASE
MEASURES
Recovery
and Neutralization:
Dike the spilled area, where this is
possible. Stop the flow of material if this is without risk. Avoid release to
the environment.
Materials
and Method of Clean-up:
Absorb
spill with inert material. Shovel material into appropriate container for
disposal.
Emergency
Measures:
Advise authorities and National Response Centre
(800-424-8802) if the has entered the water course or sewer. Notify local
health and pollution control agencies, if appropriate.
Personal
Precaution:
Keep
public away. Isolate and evacuate area. Shut off source if safe to do so.
Eliminate all ignition sources. All contaminated surface will be slippery
7. HANDLING AND STORAGE
Handling:
Advice
on Safety Handling:
For personal protection see Section 8.
Smoking, eating and drinking should be prohibited in the application area.
Avoid contact with eyes and skin. Wash thoroughly after handling.
Advice
on Protection against Fire and Explosion:
Normal
measures for preventive fire protection.
Storage:
Requirement
for Storage Area and Containers:
Electrical
installations / working materials must comply with the technological safety
standards.
Advice
on Common Storage:
No
materials to be especially mentioned.
8. EXPOSURE CONTROLS AND PERSONAL
PROTECTION
CAS#
|
Partial Chemical Name
|
OSHA TWA
|
AGIH TWA
|
Other Limit
|
64742-47-8
|
Hydrotreated Light Distilate
|
No Data
|
TLV 200mg/m3
|
No Data
|
72623-86-0
|
Lubricating Oil C15-C30
|
No Data
|
No Data
|
No Data
|
63449-39-8
|
Alpha OlephinsAlkene
|
No Data
|
No Data
|
No Data
|
61789-86-4
|
Synthetic Calcium Sulfonates
|
No Data
|
No Data
|
No Data
|
9002-84-0
|
Ethene, Tetrafluoro, Hoopolymer
|
No Data
|
No Data
|
No Data
|
6774-96-7
|
Solvent, Low Aromatic
|
500ppm
|
100ppm
|
No Data
|
9. PHYSICAL AND CHEMICAL
PROPERTIES
Physical and General Status:
Appearance:
Amber liquid
with appearance of oil.
Odor:
Slight
odor of motor oil.
Physical
State: Liquid.
PH:
Not
Applicable
Vapor
pressure for component: 33.00MM Hg @ 20°
C.
Vapor
density: Air = 1.
Heavier than Air.
Boiling Point: Greater than 153° C. @
760.00 mm Hg. Stable under normal conditions.
Melting point: Not
Applicable
Specific gravity: 1.09
@ 25° C.
Solubility in water: Negligible.
Evaporation rate: Negligible.
Slower than ether.
Flash point: Cleveland
PMCC (Closed Cup) 83 Deg. C
Percent volatile: Less
than 25%
VOC
Content: 2.4%
10. STABALITY AND REACTIVITY
Chemical
Stability:
The product is stable
Reaction to elevated temperatures:
Elevated temperatures and strong alkalis’ will promote the decomposition of the
product. The thermal decomposition is a time/temperature relationship. At room
temperature, decomposition is virtually nil.
Conditions
to avoid: No specific data
other than elevated temperatures for extended periods of time.
Incompatibility:
No specific data.
Hazardous
Polymerization:
Not know to polymerize.
Hazardous
Decomposition: Incomplete combustion can produce carbon
dioxide and or carbon monoxide.
11. TOXICOLOGICAL
INFORMATION
Toxicokinetics:
Absorption:
Routes of entry anticipated: Oral, Dermal and Inhalation.
Metabolism:
Not available
Distribution:
Not available.
Elimination:
Not available
Potential acute health
effects:
Eyes:
No know significant effects or critical hazards but may cause mild irritant.
Skin: Prolonged or repeated contact can
de-fat the skin and lead to irritation and or dermatitis. Ingestion
effect: May be fatal if swallowed or vomited and enters airways. May cause
irritation of the mouth, throat and gastrointestinal tract.
Inhalation data: Inhalation
of oil mist or vapors at elevated temperatures may cause respiratory
irritation.
Chronic effect: No significant effect or critical
hazard.
Carcinogenicity: No
component of this product at levels greater than 0.1% is identified as a
carcinogen by ACGIH, the international Agency for Research of Cancer (IRAC) or
the European commission (EC)
Epidemiology: No specific data
Teratology: No specific data
Reproductive effects: No known significant effects or critical
hazards.
Neurotoxicity: No specific data
Mutagenicity: No
component of this product at levels greater than 0.1% is classified by
established regulatory criteria as a mutagen.
Synergistic Products: No specific data.
Over
Exposure Sign/symptoms:
Inhalation: No
specific data.
Ingestion: No
specific data.
Skin: No
specific data.
Eyes: No
specific data.
Potential
Chronic Health Effects:
Conclusion summary: Not
available
Acute Toxicity:
Conclusion/ Summary: Not
available
Irritation/corrosion:
Conclusion
Summary: Eye irritation: Eye irritant.
12. ECOLOGICAL INFORMATION
Ecotoxicity: This product
should be considered toxic to aquatic organisms, with the potential to cause
lasting adverse effect in the aquatic environment. Persistence
and Degradability: Expected to be inherently biodegradable.
Bioaccumulation: Has no potential for Bioaccumulation.
Physical/chemical: Refer to sections 9 and 10.
Mobility: This
product has a specific gravity greater than water and has low water solubility.
The product is not likely to volatilize rapidly into the air because of its low
vapor pressure.
Other Adverse effects: No known significant effects or critical
hazards.
PBT:
Not available.
13. DISPOSAL CONSIDERATIONS
Description of Waste: This material may
be flammable liquid waste.
Method
of Disposal:
Handle in accordance with applicable local,
state, province and federal regulations. Package, store, transport and dispose
of all clean-up material and contaminated equipment in accordance with all
applicable federal, state, province and local health authorities and
environmental regulations. Shipments of waste material may be subject to
manifesting requirements per applicable regulations. Appropriate disposal will
depend on nature of the waste material and should be performed by competent and
properly permitted contractors. Please Recycle. Used oil may be returned to any
oil collection center for re-refining.
Method of contaminated Packaging disposal:
Empty
containers should be drained and discarded or recycled, if possible. Dispose of
in accordance with federal, state, provincial and local regulations.
14. TRANSPORTATION
Classification: Flammable
Liquids
|
Category 4
|
Skin
Corrosion/Irritation
|
Category 3
|
Germ
Cell Mutagenicity
|
Category 1B
|
Carcinogenicity
|
Category 1B
|
Aspiration
Toxicity
|
Category 1
|
Acute
Aquatic
|
Category 2
|
Chronic
Acute Toxicity
|
Category 2
|
Land
Transport (US DOT)
DOT Proper Shipping
Name: Combustible Liquid, n.o.s.
(Petroleum distillates, Alkenes)
DOT Hazard Class: 3 COMBUSTIBLE LIQUID
UN/NA NUMBER: 1268 Packing Group III
This product, in all containers
up to 1.3 Gallons in size, is deemed to be a “Limited Quantity” and exempt from
labeling and specification packaging requirements pursuant to
49 CFR 173.150 (b)(3).
For
any container over 1.3 Gallons in size, the following shall apply:
Land
Transport Canadian
TDG
Shipping Name: Environmentally
hazardous substance, liquid n.o.s. (Petroleum Distallates, Alkenes)
UN
Number: 3082
Packing Group III
Hazard
Class: 9 TDG
Classification
Land
transport (European ADR/RID):
ADR/RID
Shipping Name: Environmentally Hazardous Substances, Liquid, n.o.s. (Petroleum
Distillates, Alkanes)
UN
Number: 3082
Packing Group III
Hazard
Class: 9
Marine
Transport (IMDG/IMO):
IMDG/IMO
Shipping Name: Environmentally hazardous substance, liquid n.o.s. (Petroleum
Distillates, Alkenes)
UN
Number: 3082
Hazard
Class: 9 IMDG MFAG
Number:
Marine
Pollutant: Yes
IMDG
EMS Page:
ICAO/IATA
Shipping Name: Environmentally hazardous substance, liquid n.o.s. (Petroleum
Distillates, Alkenes)
UN
Number: 3082 Packing Group
III
Hazard Class: 9
15. REGULATORY INFORMATION
CAS#
|
Hazardour Component
|
S.302(EHS)
|
S304 RQ
|
S313(TRI)
|
64742-47-8
|
Hydro-treated Light Distillate
|
No
|
No
|
No
|
72623-86-0
|
Lubricating Oil C15-C30
|
No
|
No
|
No
|
63449-39-8
|
Alpha OlephinsAlkene
|
No
|
No
|
No
|
61789-86-4
|
Synthetic Calcium Sulfonates
|
No
|
No
|
No
|
9002-84-0
|
Ethene, Tetrafluoro, Hoopolymer
|
No
|
No
|
No
|
16. OTHER INFORMATION
Revision
Date: 07/27/2015
Preparer
Name: RJS
Hazard
Rating System:
Key/Legend
NFPA:
Health 1,
Flammability 2, Instability 0, Special Hazard Nil.
Hazard
Scale: 0= Minimal, 1 =
Slight, 2= Moderate, 3= Serous, 4= Severe
HMIS:
Health
1, Flammability 2, Physical 0, Other None
Hazard Scale: 0= Minimal, 1= Slight, 2= Moderate,
3= Serious, 4= Severe (Chronic Hazard)
Hazardous
Material Identification Systems (HMS)
Health
1- Slight
Flammability
2- Moderate
Physical
0- Minimal
Other
- None
Additional
Information about this Product: No Data Available
Company
Policy or Disclaimer:
NOTICE: The information presented herein is
given in good faith, but no warranty, expressed or implied, is made. This
information in no way amends, enlarges, modifies, or creates a specification or
warranty, and all WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING WITHOUT
LIMITATION THE WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR
PURPOSE, ARE HEREBY EXCLUDED. This information is a recommendation for safe
handling, use, storage, disposal, transportation, and release and Supplier
shall not be responsible for any damage or injury resulting from abnormal use,
from any failure to follow appropriate practices, or from hazards inherent in
the nature of the product and or material. This information relates only to the
specific product and/or material designated and may no be valid or such product
and/or material used in combination with any other product and/or material or
in any purpose, unless otherwise specified
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